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The point of attack of a chlorine atom on trichloroethylene

par Bertrand, L.;Franklin, James A. ;Goldfinger, Paul ;Huybrechts, Guy
Référence Journal of Physical Chemistry (1952), 72, 11, page (3926-3928)
Publication Publié, 1968

Article révisé par les pairs

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Résumé :

The chlorine-photosensitized oxidations of C2HCl3, 1,1,1,2-C2H2Cl4, and 1,1,2,2-C2H2Cl4 have been studied at 357°K. From a comparison of the products of these long-chain reactions it can be concluded that the rate constant for the addition of a chlorine atom to the less chlorinated carbon atom in trichloroethylene is at least eight times greater than that for addition to the more chlorinated one.