par Goldfinger, Paul 
;Huybrechts, Guy ;Martens, Guy ;Meyers, Liliane ;Olbregts, Jean
Référence Transactions of the Faraday Society, 61, page (1933-1938)
Publication Publié, 1965
;Huybrechts, Guy ;Martens, Guy ;Meyers, Liliane ;Olbregts, Jean Référence Transactions of the Faraday Society, 61, page (1933-1938)
Publication Publié, 1965
Article révisé par les pairs
| Résumé : | The inhibitory effect of oxygen on the photochlorination of ethane has been studied between 253 and 423°K. It can be explained by the removal of ethyl radicals by molecular oxygen: C2H5+O2→ C2H5O2 k9. The value k9 = 0.63 × 109 mole-1 l. sec-1 is in good agreement with literature data. The dependence of the rate on concentrations and light intensity is discussed and permits one to discard an alternative explanation involving the reaction Cl+O2→ClO2. |
