par Fadel, Antoine;Legrand, Frederic;Evano, Gwilherm ;Rabasso, Nicolas
Référence Advanced synthesis & catalysis, 353, page (263-267)
Publication Publié, 2011
Référence Advanced synthesis & catalysis, 353, page (263-267)
Publication Publié, 2011
Article révisé par les pairs
Résumé : | A highly regio- and stereoselective, nickel(II)-catalyzed procedure for the hydrophosphonylation of ynamides has been developed. This protocol provides a straightforward and efficient entry to a series of beta-aminovinylphosphonates that can easily be prepared in good yields from a wide range of ynamides and dialkyl phosphites as well as useful insights into the reactivity of ynamides under nickel catalysis. |