par Gomila, Antoine;Le Poul, Nicolas;Cosquer, Nathalie;Kerbaol, Jean-Michel;Noël, Jean-Marc;Reddy, Madhusudana T;Jabin, Ivan ;Reinaud, Olivia;Conan, Françoise;Le Mest, Yves
Référence Dalton transactions, 39, 48, page (11516-11518)
Publication Publié, 2010
Référence Dalton transactions, 39, 48, page (11516-11518)
Publication Publié, 2010
Article révisé par les pairs
Résumé : | We report the self-induced "electroclick" immobilization of the [Cu(II)(6-ethynyl-TMPA)(H(2)O)](2+) complex, by its simple electro-reduction, onto a mixed azidoundodecane-/decane-thiol modified gold electrode. The redox response of the grafted [Cu(II/I)(TMPA)] at the modified electrode is fully reversible indicating no Cu coordination change and a fast electron transfer. |