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Fluoride binding in water: a new environment for a known receptor.

par Cametti, Massimo ;Dalla Cort, Antonella;Bartik, Kristin
Référence ChemPhysChem, 9, 15, page (2168-2171)
Publication Publié, 2008-10

Article révisé par les pairs

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Résumé :

(Figure Presented) Binding in a micelle: In the presence of CTABr micelles (see picture), the salophen-UO2 complex 1 binds fluoride in water with the highest affinity ever recorded for a neutral receptor (K≈ ca. 104M-1). The receptor's location and its orientation within the micellar system are determined by PRE and NOE NMR experiments. © 2008 Wiley-VCH Verlag GmbH& Co. KGaA.