Lactoperoxidase-catalyzed iodination of arachidonic acid: formation of macrolides.

Boeynaems, Jean-Marie; Reagan, D; Hubbard, W. C.

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Lactoperoxidase-catalyzed iodination of arachidonic acid: formation of macrolides.

par Boeynaems, Jean-Marie

;Reagan, D ;Hubbard, W. C.
Référence Lipids, 16, 4, page (246-249)
Publication Publié, 1981-04

Article révisé par les pairs

Résumé :

In the presence of iodide and hydrogen peroxide, lactoperoxidase catalyzed the conversion of arachidonic acid into several iodinated products; the major one was previously identified as an iodo-delta-lactone. Two minor and less polar products have now been characterized as 15-iodo-14-hydroxyeicosatrienoic acid, omega-lactone and 14-iodo-15-hydroxyeicosatrienoic acid, omega-lactone, on the basis of 125I incorporation, mass spectrometry, proton magnetic resonance spectroscopy and chemical modifications.

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