par Torres Huerta, Aaron 
;Velásquez-Hernández, Miriam de J.;Lempereur, Sven;Troian‐Gautier, Ludovic;Veronesi, Giulia;Valkenier, Hennie
Référence Cell reports physical science, 7, page (103312)
Publication Publié, 2026-05-01
;Velásquez-Hernández, Miriam de J.;Lempereur, Sven;Troian‐Gautier, Ludovic;Veronesi, Giulia;Valkenier, Hennie Référence Cell reports physical science, 7, page (103312)
Publication Publié, 2026-05-01
Article révisé par les pairs
| Résumé : | Precise stoichiometric control in multimetallic lanthanide nanosystems is essential for optical devices, sensing, and bioimaging applications owing to their composition-dependent emission properties. However, controlling metal composition, spatial distribution, intermetallic energy transfer, and colloidal stability remains challenging. Here, we report a liposome-based nanoreactor platform that enables the in situ formation of multivariate TbxEuy-dicarboxylate complexes, enabling finely tuned lanthanide stoichiometry within attoliter-scale confined volumes. Liposomes pre-loaded with specific Tb3+:Eu3+ ratios are combined with a synthetic anion transporter that mediates dicarboxylate transport through lipid membranes, enabling controlled coordination reactions in aqueous solution. This method, coupled with the use of a blue-emissive ligand, supports continuous color tuning across the entire RGB spectrum. Real-time emission spectroscopy reveals faster photoluminescence appearance for Eu3+ than Tb3+, providing experimental insight into lanthanide reactivity under nanoscale confinement. These findings position liposome-based nanoreactors as a versatile platform for investigating coordination reactions and engineering multimetallic luminescent colloidal materials in aqueous media. |
