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Eco-Friendly Carbon Nanotubes Reinforced with Sodium Alginate/Polyacrylic Acid for Enhanced Adsorption of Copper Ions: Kinetics, Isotherm, and Mechanism Adsorption Studies

par Chang, Pengbo;Zhou, Shuyang;Wang, Tongchao;Hua, Dangling;Liu, Shiliang;Okoro, Oseweuba ;Shavandi, Armin ;Nie, Lei
Référence Molecules (Print Archive Edition), 29, 19, page (4518)
Publication Publié, 2024-10-01

Article révisé par les pairs

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Résumé :

This study investigates the removal efficiency of Cu2+ from wastewater using a composite hydrogel made of carbon nanotubes (CNTs), sodium alginate (SA), and polyacrylic acid (PAA) prepared by free radical polymerization. The CNTs@SA/PAA hydrogel’s structure and properties were characterized using SEM, TEM, FTIR, XRD, rheology, DSC, EDS, elemental mapping analysis, and swelling. The adsorption performance for Cu2+ was tested in batch adsorption experiments, considering the pH, dosage, initial concentration, and contact time. The optimal conditions for Cu2+ removal were pH 5.0, an adsorbent dosage of 500 mg/L, and a contact time of 360 min. The adsorption followed pseudo-second order kinetics. Isotherm analyses (Langmuir, Freundlich, Temkin, Dubinin–Radushkevich, Sips, Toth, and Khan) revealed that the Freundlich isotherm best described the adsorption, with a maximum capacity of 358.52 mg/g. A thermodynamic analysis indicated that physical adsorption was the main interaction, with the spontaneity of the process also demonstrated. This study highlights the high efficiency and environmental friendliness of CNT@SA/PAA composites for Cu2+ removal from wastewater, offering a promising approach for water treatment.