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Decarbonisation potential of dimethyl ether/hydrogen mixtures in a flameless furnace: Reactive structures and pollutant emissions

par Sharma, Saurabh ;Savarese, Matteo ;Coussement, Axel ;Parente, Alessandro
Référence International journal of hydrogen energy, 48, page (2401-2427)
Publication Publié, 2022-11-03

Article révisé par les pairs

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Résumé :

This article sheds light on the combustion characteristics of dimethyl ether and its mixtures with methane/hydrogen under flameless conditions at different equivalence ratios. It was found that combustion of 100% dimethyl ether in flameless conditions minimises the NO formation, keeping it less than 10 ppm with no CO or unburned hydrocarbons. Progressive addition of methane was found to reduce the NO, reaching up to zero value at 50% methane in molar fraction along with a marginal CO2 reduction. However, large amounts of CO were found for higher methane levels, greater than 60% CH4 in molar fraction. Reactive structures based on OH∗ chemiluminescence revealed that adding methane results in increased ignition delay times and, consequently, a more distributed reaction zone characterised by reduced temperature gradients. No visible flame was observed for pure dimethyl ether as well as dimethyl ether/methane mixtures. Furthermore, a more intense and narrower reaction zone, characterised by the presence of a visible flame, was formed upon hydrogen addition. Adding hydrogen by 50% in molar fraction did not cause a noticeable rise in NO levels; however, CO2 was lowered by about 18%. Further addition of hydrogen resulted in increased peak temperatures of about 1700 K and higher NO emissions of about 50 ppm. Additionally, a skeletal Chemical Reactor Network was built and simulated with the commercial software CHEMKIN Pro to investigate the effect of the different mixtures and operating conditions on NO formation from a chemical point of view. N2O pathway was observed to be the root source of NO emissions for pure DME and DME/CH4 mixtures, however; the thermal pathway became gradually more important as hydrogen concentration was increased in the mixture.