par Annibaletto, Julien 
;Jacob, Clément ;Theunissen, Cédric
Référence Organic letters, 24, 23, page (4170-4175)
Publication Publié, 2022-06-01
;Jacob, Clément ;Theunissen, Cédric Référence Organic letters, 24, 23, page (4170-4175)
Publication Publié, 2022-06-01
Article révisé par les pairs
| Résumé : | Ammonium salts are usually considered as highly challenging to reduce into the corresponding radicals because of the strength of their carbon-nitrogen bond. Here, we disclose that several ammonium salts can be readily activated using iridium photoredox catalysis to form radicals and illustrate the synthetic utility of this activation of strong C-N bonds with hydrodeamination reactions and radical couplings. Cyclic voltammetry was exploited to rationalize the reactivity observed for the activation of these ammonium salts. |
