par Thilmany, Pierre
;Guarnieri-Ibáñez, Alejandro;Jacob, Clément
;Lacour, Jérome;Evano, Gwilherm ![](/vufind/images/ULB/publications_list.png)
Référence ACS Organic & Inorganic Au, 2, page (53-58)
Publication Publié, 2022-02-01
![](/vufind/images/ULB/publications_list.png)
![](/vufind/images/ULB/publications_list.png)
![](/vufind/images/ULB/publications_list.png)
Référence ACS Organic & Inorganic Au, 2, page (53-58)
Publication Publié, 2022-02-01
Article révisé par les pairs
Résumé : | An original and straightforward entry to polysubstituted indenes from readily available ynamides is reported. Upon reaction with a NHC-gold complex under mild conditions, activated keteniminium ions are generated whose unique electrophilicity triggers a [1,5]-hydride shift and a subsequent cyclization. The presence of an endocyclic enamide in the densely functionalized resulting indenes was shown to be especially useful and versatile, offering a range of opportunities for their further post-functionalization. |