par De Laet, Marc-Henri ;Tilquin, Bernard
Référence Bulletin des Sociétés chimiques belges, 100, 2, page (97-105)
Publication Publié, 1991
Article révisé par les pairs
Résumé : Stable products from the photolysis of HI in methyl‐3 pentane (3 MP) or dimethyl‐2,3 butane (23 DMB) quenched solid at 77 K are analyzed by capillary gas chromatography. Selective formation of a tertiary radical is proposed for the 23 DMB/HI system; in 3 MP/HI, C‐H bond rupture is also localized at the weakest tertiary bond, however the scission is not selective. Copyright © 1991 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim

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