par Bevernaegie, Robin ;Marcelis, Lionel ;Moreno-Betancourt, Angélica;Laramée-Milette, Baptiste;Hanan, Garry S.;Loiseau, Frédérique;Sliwa, Michel;Elias, Benjamin
Référence PCCP. Physical chemistry chemical physics, 20, 43, page (27256-27260)
Publication Publié, 2018-11-01
Article révisé par les pairs
Résumé : Time-resolved spectroscopy was exploited to gain new insights into the nature and dynamics of charge transfer excited states of bis-cyclometalated Ir(iii) complexes. We showed that its dynamics is strongly influenced by the nature of the diimine ligand due to the existence of a ligand-ligand charge transfer process in the picosecond timescale. All the results are supported by DFT/TD-DFT calculations and spectroelectrochemistry.

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