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Statistical mechanics of solid and liquid mixtures of ortho- and para-hydrogen: II

par Babloyantz, Agnessa ;Bellemans, André
Référence Molecular Physics, 3, 4, page (313-318)
Publication Publié, 1960-07

Article révisé par les pairs

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Résumé :

Various refinements are added to a previous theoretical calculation of the configurational free energy of condensed mixtures of o- and p-hydrogen, based on an oversimplified statistical model: (a) account is taken of the fact that the forces acting between o- and p-molecules are somewhat different and (b) the rigid lattice model previously used is replaced by an ensemble of Einstein oscillators. A better agreement with experiment is reached. © 1960 Taylor & Francis Group, LLC.