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Transmembrane transport of copper(I) by imidazole-functionalised calix[4]arenes

par Renier, Nathan ;Reinaud, Olivia;Jabin, Ivan ;Valkenier, Hennie
Référence Chemical communications, 56, 59, page (8206-8209)
Publication Publié, 2020-06-10

Article révisé par les pairs

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Résumé :

Here we present the first synthetic transmembrane transporters for Cu+. Calix[4]arenes with two imidazole groups have a linear coordination motif, which allows selective extraction of Cu+ into chloroform. Transmembrane transport of Cu+ into liposomes was investigated with a newly developed assay and the results open the way to biomedical applications of these Cu+ ionophores.