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Modelling of contact lines on heterogeneous substrates : stick-slip and contact angle hysteresis

par Hatipogullari, Metin
Président du jury Lambert, Pierre
Promoteur Colinet, Pierre
Publication Non publié, 2020-04-24

Thèse de doctorat

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Résumé :

This thesis highlights generic aspects of contact angle hysteresis and stick-slip motion,encountered in most practical wetting situations.First, we study the scaling relation between the heterogeneity strength and the amplitudeof the contact angle hysteresis it induces in the model configuration of a chemicallyheterogeneous microchannel. A key parameter which determines the qualitativefeatures is the heterogeneity wavelength. In particular, we identify a near-thresholdbehavior where the quadratic scaling between the heterogeneity amplitude and the resultinghysteresis, already known for a dilute system of wetting defects, is explainedby the closeness to the threshold, and a macroscopic limit without observable stick-slipwhere this scaling is linear.In the second part, we adapt the description to the configuration of a meniscusaround a wavy fibre. This adaptation brings the generic results of the first part in thereach of experiments. A comparison with experiments is achieved at the level of theindividual topography-induced jumps.In the third part, we expand the formulation to treat the quasi-steady interface shapecontact line dynamics and study how the the presence of stick-slip motion at the observableor unobservable scale modifies the scaling relation between the contact linevelocity and contact angle. We recover the known result that the scaling exponent dependson the nature of the externally controlled parameter, identify the causes of thisdependency in the corresponding static limits, and predict the disappearance of this dependencyabove a critical velocity which decreases with the heterogeneity wavelength.Finally, we show trough examples how the modelling framework which permitscapturing contact angle hysteresis and stick-slip motion in a minimalistic way can beadopted to treat configurations with a finite amount of contact points, or the 3D problemof a drop with a deformed contact line. We discuss the arising configuration-specificeffects, also in configurations of biomimetic interest.