par Hammons, Joshua;Ustarroz Troyano, Jon 
;Muselle, Thibault;Torriero, Angel;Terryn, Herman ;Suthar, Kamlesh;Ilavsky, Jan
Référence Journal of Physical Chemistry C, 120, 3, page (1534-1545)
Publication Publié, 2016
;Muselle, Thibault;Torriero, Angel;Terryn, Herman ;Suthar, Kamlesh;Ilavsky, JanRéférence Journal of Physical Chemistry C, 120, 3, page (1534-1545)
Publication Publié, 2016
Article révisé par les pairs
| Résumé : | Type III deep eutectic solvents (DES) have attracted significant interest as both environmentally friendly and functional solvents that are, in some ways, advantageous to traditional aqueous systems. While these solvents continue to produce remarkable thin films and nanoparticle assemblies, their interactions with metallic surfaces are complex and difficult to manipulate. In this study, the near-surface region (2–600 nm) of a carbon surface is investigated immediately following silver nanoparticle nucleation and growth. This is accomplished, in situ, using a novel grazing transmission small-angle X-ray scattering approach with simultaneous voltammetry and electrochemical impedance spectroscopy. With this physical and electrochemical approach, the time evolution of three distinct surface interaction phenomena is observed: aggregation and coalescence of Ag nanoparticles, multilayer perturbations induced by nonaggregated Ag nanoparticles, and a stepwise transport of dissolved Ag species from the carbon surfa... |
