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Measurement of Soret coefficients in a ternary mixture of toluene-methanol-cyclohexane in convection-free environment

par Mialdun, Aliaksndr ;Ryzhkov, Ilya ;Khlybov, Oleg;Lyubimova, Tatyana;Shevtsova, Valentina
Référence The Journal of Chemical Physics, 148, 4, 044506
Publication Publié, 2018-01

Article révisé par les pairs

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Résumé :

We report on the measurement of Soret (ST) coefficients in the ternary system toluene (T)-methanol (M)-cyclohexane (Ch) onboard the International Space Station in the experiment selectable optical diagnostic instrument/DCMIX2 (Diffusion Coefficients Measurement in ternary mIXtures). Nine experiments were conducted in the range of mean temperatures between 298.15 K and 306.15 K in the mixture with composition 0.62 (T)-0.31 (M)-0.07 (Ch) in mass fractions. A linear dependence of the Soret coefficients on temperature was established for the ternary mixture. It has also been found that, over considered range of mean temperatures, the Soret coefficients of toluene are small and positive, while the Soret coefficients for methanol are negative and, at least, two times larger. The present work also presents a comprehensive study of possible methodologies to process raw data from the Soret experiment in ternary mixtures. All the experiments were processed by seven different schemes and two of them were identified as the most reliable. We also investigate the error propagation and explain the reasons for the discrepancy of the results obtained by different schemes.