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Heat capacity anomalies along the critical isotherm in fluid-fluid phase transitions

par Losada Perez, Patricia ;Perez Sanchez, German;Troncoso, Jacobo;Cerdeirina, CA
Référence The Journal of Chemical Physics, 132, page (154509)
Publication Publié, 2010-04-21

Article révisé par les pairs

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Résumé :

The behavior of the isochoric heat capacity of pure fluids and the isobaric heat capacity at constant composition of binary mixtures along isothermal paths of approach to liquid-gas and liquid-liquid critical points is studied. From the complete scaling formulation of fluid-fluid criticality, explicit expressions for the critical amplitudes of the leading