• Citer

Chlorine‐photosensitized oxidations of chloroethanes and chloroethylenes in the gas phase

par Bertrand, L.;Meyers, Liliane ;Franklin, James A. ;Huybrechts, Guy ;Olbregts, Jean
Référence International journal of chemical kinetics, 3, 1, page (89-96)
Publication Publié, 1971

Article révisé par les pairs

• Détails
• Contenu

Résumé :

Long‐chain chlorine‐photosensitized oxidation has been observed in the gas phase at about 355°K for 1,1,2,2‐ and 1,1,1,2‐C2H2Cl4, C2HCl5, and C2Cl4 but not for C2H6, 1,2‐C2H4Cl2, 1,1,1‐C2H3Cl3, C2H4, and 1,2‐C2H2Cl2. This is shown to depend on the exothermicity of the dissociation of the chloroethoxy radicals which must be involved in each reaction system. Copyright © 1971 John Wiley & Sons, Inc.