par Nasielski, Jacques ;Guiette-Limbourg, Viviane
Référence Bulletin des Sociétés chimiques belges, 81, 1, page (351-356)
Publication Publié, 1972
Article révisé par les pairs
Résumé : Symmetrically ring‐substituted stilbene meso dibromides are dehalogenated by iodide ions in acetone with rates depending on the substituent. The HAMMETT pσ correlation for this E2 concerted elimination is however a curve showing a well‐defined minimum (fig. 1) rather than a straight line. This behaviour is ascribed to the very high polarizability of the transition state. Copyright © 1972 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim