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Poincaré's theorem and unitary transformations for classical and quantum systems

par Petrosky, Tomio T.Y.;Prigogine, Ilya
Référence Physica. A, 147, 3, page (439-460)
Publication Publié, 1987

Article révisé par les pairs

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Résumé :

Poincaré's celebrated theorem on the nonexistence of analytical invariants of motion is extended to the case of a continuous spectrum to deal with large classical and quantum systems. It is shown that Poincaré's theorem applies to situations where there exist continuous sets of resonances. This condition is equivalent to the nonvanishing of the asymptotic collision operator as defined in modern kinetic theory. Typical examples are systems presenting relaxation processes or exhibiting unstable quantum levels. As the result of Poincaré's theorem, the unitary transformation, leading to a cyclic Hamiltonian in classical mechanics or to the diagonalization of the Hamiltonian operator in quantum mechanics, diverges. We obtain therefore a dynamical classification of large classical or quantum systems. This is of special interest for quantum systems as, historically, quantum mechanics has been formulated following closely the patterns of classical integrable systems. The well known results of Friedrichs concerning the coupling of discrete states with a continuum are recovered. However, the role of the collision operator suggests new ways of eliminating the divergence in the unitary transformation theory.