par Phuong, Nguyen Thu;Buess Herman, Claudine
;Thom, Nguyen Thi;Nam, Pham Thi;Lam, Tran Dai;Thanh, Dinh Thi Mai
Référence Green Processing and Synthesis, 5, 6, page (537-547)
Publication Publié, 2016-12

Référence Green Processing and Synthesis, 5, 6, page (537-547)
Publication Publié, 2016-12
Article révisé par les pairs
Résumé : | A metal organic framework (MOF) material based on Cu-BTC, which is formed from Cu and benzene-1,3,5-tricarboxylic acid (H3BTC), with 1D and 3D structures was synthesized under potential control. Cu-BTC 3D was electrodeposited at an applied potential of 5 V using tetrabutylammonium tetrafluoroborate (TBATFB) as electrolyte during 10-60 min. Hydration showed that the phase structure of Cu-BTC 3D did not change after a short time of immersing in water and that the specific surface area increased from 48 m2/g to 371 m2/g. In contrast, with a long time of hydration (more than 4 h), Cu-BTC was destroyed and a dehydration process could not recover the Cu-BTC structure. |