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Synthesis and Characterization of (Z)‐1‐[2‐(Triarylstannyl)vinyl]‐1‐Cyclohexanols and their Arylhalostannyl Derivatives

par Fu, FangXin;Lin, Shan Xi;Jie, Fu Yu;Pan, Huade;Mahieu, Bernard;Gielen, Marcel ;Kayser, François;Willem, Rudolph
Référence Zeitschrift für anorganische und allgemeine Chemie, 620, 6, page (1006-1010)
Publication Publié, 1994

Article révisé par les pairs

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Résumé :

1‐Ethynyl‐1‐cyclohexanol reacts with a triaryltin hydride Ar3SnH (Ar = phenyl, p‐tolyl) and generates the corresponding (Z)‐1‐[2‐(triarylstannyl)vinyl]‐1‐cyclohexanol. The product obtained reacts with one or two equivalents of halogen (ICl or I2) to form the associated (Z)‐1‐[2‐(diarylhalostannyl)‐vinyl]‐1‐cyclohexanol or (Z)‐1‐[2‐(aryldihalostannyl)vinyl]‐1‐cyclohexanol, respectively. All compounds were characterized by elemental analysis, 1H, 13C, 119Sn NMR and Mössbauer spectroscopy. Copyright © 1994 Verlag GmbH & Co. KGaA, Weinheim