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Organometallic Compounds. XXIV. () Determination of all the possible isomerization reactions of coordination complexes by the use of permutations

par Gielen, Marcel ;Vanlautem, Noel
Référence Bulletin des Sociétés chimiques belges, 79, 11-12, page (679-687)
Publication Publié, 1970

Article révisé par les pairs

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Résumé :

Permutations may be used to describe the transformations of a given complex MLn into one of the n!/hr, possible isomers. The determination of the n! possible permutations gives all the isomerization paths of this complex occuring by nonbond‐rupture mechanisms. This is applied to the case of four; five‐ and six‐ coordinate structures and might be applied as well to higher coordination numbers. Copyright © 1970 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim