par Olbregts, Jean
Référence International journal of chemical kinetics, 6, 3, page (395-400)
Publication Publié, 1974
Article révisé par les pairs
Résumé : Different possible mechanisms for the gas phase reaction of formation of bromine chloride from bromine and chlorine are discussed. The rate of the reaction has been deduced from photometric measurements in conventional static reactors of surface‐to‐volume ratio ranging between 0.6 and 3 cm−1, at temperatures between 51 and 113°C. Experimental data show that (1) the observed reaction is predominantly heterogeneous, and (2) the homogeneous reaction must proceed by an atomic chain mechanism initiated by Br atoms. Copyright © 1974 John Wiley & Sons, Inc.