par Gorsane, Mohamed ;Martin, Ricardo
Référence Bulletin des Sociétés chimiques belges, 94, 3, page (205-214)
Publication Publié, 1985
Article révisé par les pairs
Résumé : 1‐Fluoropentahelicene and substituted derivatives have been synthesized by the photocyclodehydrogenation of 1,2‐di(2‐naphthyl) ethylenes (1) and 3‐styrylphenanthrenes (2). In two cases (la and 2d) the photocyclisations gave rise to benzo [g,h,i] perylenes (7, 8, 23, 24) a reaction involving either the loss (8, 24) or the migration (7, 23) of the fluorine atom. The 1H‐NMR spectra are described. Copyright © 1985 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim