par De Brouckère, Lucia ;Anspach, Claude
Référence Bulletin des Sociétés chimiques belges, 61, 11-12, page (622-634)
Publication Publié, 1952
Article révisé par les pairs
Résumé : Turbidity measurements were made with solutions of polystyrene (molecular weight 206.000) in mixtures of toluene with normal hexane, normal heptane, ether, dioxane, acetone, butanone, cyclohexanone and secondary butanol. Application of Kirkwood and Goldberg's theory lead to the conclusion that toluene was “in general” adsorbed by the polymer particles. No adsorption was found in mixtures of toluene with cyclohexanone and practically none in mixtures of toluene with dioxane. No connection was found between interaction coefficients and cohesive energy values. Copyright © 1952 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim