par Kirsch-De Mesmaeker, Andrée ;Nasielski, Jacques ;Willem, Rudolph
Référence Bulletin des Sociétés chimiques belges, 91, 9, page (731-742)
Publication Publié, 1982
Article révisé par les pairs
Résumé : The influence of the pH on the photoelectrochemical behavior of Ru(bpy)3 2+ is examined at a highly doped SnO2 electrode. An important photocurrent increase from pH 11 to 13 is explained by the photochemical production of a long‐lived reductant generated from Ru(bpy)3 2+. Photocurrent observations at metallic electrodes and the photogalvanic cell behavior confirm this interpretation. Furthermore, a modification of the SnO2 electrode by the ruthenium complex has been pointed out. Copyright © 1982 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim

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