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Synthesis of the First Optically Active Tetraorganotin Compound in Which the Tin Atom Is The Only Chiral Center

par Gielen, Marcel ;Mokhtar-Jamaï, Hassan
Référence Bulletin des Sociétés chimiques belges, 84, 3, page (197-202)
Publication Publié, 1975

Article révisé par les pairs

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Résumé :

The synthesis of optically active p‐anisyl‐(3‐hydroxy‐3‐methylbutyl)methyl‐α‐naphthyl tin (IV) is described. The spectroscopic properties of this compound and of the products used as synthesis intermediates are given. The two diastereoisomers of (‐)‐menthyl‐β‐(methylnaphthyl‐phenylstannyl)‐propionate (V) could not be separated. Copyright © 1975 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim