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On the spectroscopic consequences of different tunnelling mechanisms in non-rigid RPF4 molecules (R = CI, CH3)

par Fastenakel, Daniel ;Brocas, Jean
Référence Molecular Physics, 40, 2, page (361-380)
Publication Publié, 1980-06

Article révisé par les pairs

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Résumé :

In this paper we obtain the theoretical spectra for each possible mechanism for fluorine exchange in RPF4 molecules (R = Cl, CH3). The number of lines and their relative intensities are a characteristic of each isomerization mode. The possibility of discriminating between the iso-merization modes is discussed. © 1980 Taylor & Francis Ltd.