Article révisé par les pairs
Résumé : The stereochemistry and the rate of the reaction of nine vinylic organotin compounds with iodine has been studied. A highly polar transition state A is suggested in order to interpret the reactivity sequences (1) and (2), the observed salt effect and the retention of configuration of the vinyl group. (Formula Presented.) Copyright © 1968 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim