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Synthesis of (Homooxa)calixarene-Monoquinones through the "all-but-One" Methodology

par Lavendomme, Roy ;Cragg, Peter P.J.;Marcos, Paula Maria;Luhmer, Michel ;Jabin, Ivan
Référence Organic letters, 17, 22, page (5690-5693)
Publication Publié, 2015

Article révisé par les pairs

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Résumé :

The iteroselective "all-but-one" carbamatation methodology has been successfully extended to homooxacalixarenes and used for the selective and controlled synthesis of homooxacalixarene-monoquinones and calixarene-monoquinones. These moquinone derivatives constitute interesting molecular platforms that, until now, were inaccessible through any efficient means.