Article révisé par les pairs
Résumé : | In contrast with the catalytic isomerization of cis and trans-4-tertiobutylcyclohexanols, epimerization of this alcohol by a slight excess of an alkaline metal does not afford a correct measure of the relative stability of the two stereoisomers. The equilibrium which is reached depends on the metal which is used for the epimerization. © 1963 Birkhäuser Verlag. |