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Real-time evolution of the lamellar organization of poly(ethylene terephthalate) during crystallization from the melt: High-temperature atomic force microscopy study

par Ivanov, Dimitri ;Amalou, Zhor ;Magonov, Sergei
Référence Macromolecules, 34, 26, page (8944-8952)
Publication Publié, 2001-12

Article révisé par les pairs

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Résumé :

High-temperature atomic force microscopy (AFM) was used for in-situ monitoring of melt-crystallization of poly(ethylene terephthalate) (PET) at 233°C. The observed evolution of the lamellar structure allowed identification of the stack thickening process at the secondary crystallization stage. This finding explains the puzzling decrease of the small-angle X-ray scattering (SAXS) long period observed during isothermal annealing of PET. The quantitative analysis of high-temperature AFM images provides statistically meaningful parameters for the semicrystalline structure and an accurate choice of a structural model for the interpretation of SAXS data.