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Etude spectroscopique de molécules halogéneés-II. Effet de solvant sur les vibrations ν(C-Hal)

par Reisse, Jacques ;Chiurdoglu, Grégoire
Référence Spectrochimica Acta, 20, 3, page (441-451)
Publication Publié, 1964-03

Article révisé par les pairs

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Résumé :

The solvent effect on the ν(CX) vibrations of the chloro-, bromo- and iodocyclohexanes has been studied. With the aid of the H.B.W. relation, it is possible to make correlations between the solvent effect, polarity and axial of equatorial orientation of the C-X bond. On the other hand, the use of solvents mixtures gives continuous but non linear curves in K.B.M. diagrams. This behaviour is discussed. © 1964.