par Goldfinger, Paul ;Huybrechts, Guy ;Mahieu, A.;Van Der Auwera, Daniel
Référence Journal of Physical Chemistry (1952), 64, 4, page (468-470)
Publication Publié, 1960
Article révisé par les pairs
Résumé : The importance of temperature gradients (Draper effect) in gas phase photochlorination reactions is demonstrated. It is shown that this effect can lead not only to numerical errors in rate constants and activation energies but also to misinterpretations of mechanisms. A method for correcting data for this effect is given.