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Dioxygen binding of water-soluble iron(II) porphyrins in phosphate buffer at room temperature.

par Ruzié, Christian ;Even, Pascale;Boitrel, Bernard
Référence Organic & biomolecular chemistry, 5, 10, page (1601-1604)
Publication Publié, 2007-05

Article révisé par les pairs

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Résumé :

Two water-soluble tris(2-aminoethylamine) (tren) capped iron porphyrins were synthesized. The stability of their dioxygen adducts was studied in phosphate buffer, leading to half-life times around 7 min for the oxygenated species.