par Sapir, Michael;Vander Donckt, Emile
Référence Chemical physics letters, 36, 1, page (108-110)
Publication Publié, 1975-10
Article révisé par les pairs
Résumé : The rate constants of radiationless S 1 → T n and T 1 → S 0 intersystem crossing of six helicenes have been evaluated by combining emission lifetimes and quantum yields of fluorescence and triplet state formation. The data are compared to those of linear acenes. In contrast to the linear series, the photophysical properties of the helicenes evolve steadily as a function of the number of ortho-fused benzene rings. © 1976.