• Citer

Nitrogen inversion in tetrahydro-1,2-oxazines and the stereochemistry of geneserine

par Riddell, Frank;Williams, D.A.R.;Hootele, Claude ;Reid, N.
Référence Journal of the Chemical Society B: Physical Organic, page (1739-1741)
Publication Publié, 1970

Article révisé par les pairs

• Détails
• Contenu

Résumé :

The temperature variation of the n.m.r. spectrum of geneserine is explained in terms of a nitrogen-inversion process in the 1,2-oxazine ring. It is argued that the process is compatible with a cis rather than a trans ring fusion.