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Buoyancy-driven convection around exothermic autocatalytic chemical fronts traveling horizontally in covered thin solution layers

par Rongy, Laurence ;De Wit, Anne
Référence The Journal of Chemical Physics, 131, 18, page (1-9), 184701
Publication Publié, 2009

Article révisé par les pairs

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Résumé :

Spatial variations of concentrations and temperature across exothermic chemical fronts can initiate buoyancy-driven convection. We investigate here theoretically the spatiotemporal dynamics arising from such a coupling between exothermic autocatalytic reactions, diffusion, and buoyancy-driven flows when an exothermic autocatalytic front travels perpendicularly to the gravity field in a thin solution layer. To do so, we numerically integrate the incompressible Stokes equations coupled to evolution equations for the concentration of the autocatalytic product and temperature through buoyancy terms proportional to, respectively, a solutal RC and a thermal RT Rayleigh number. We show that exothermic fronts can exhibit new types of dynamics in the presence of convection with regard to the isothermal system. In the cooperative case (RC and RT are of the same sign), the dynamics asymptotes to one vortex surrounding, deforming, and accelerating the front much like in the isothermal case. However, persistent local stratification of heavy zones over light ones can be observed at the rear of the front when the Lewis number Le (ratio of thermal diffusivity over molecular diffusion) is nonzero. When the solutal and thermal effects are antagonistic (RC and R T of opposite sign), temporal oscillations of the concentration, temperature, and velocity fields can, in some cases, be observed in a reference frame moving with the front. The various dynamical regimes are discussed as a function of RC, RT, and Le. © 2009 American Institute of Physics.