par Sanfeld, Albert 
;Steinchen, Annie
Référence Transactions of the Faraday Society, 62, 523, page (1907-1914)
Publication Publié, 1966
;Steinchen, Annie Référence Transactions of the Faraday Society, 62, 523, page (1907-1914)
Publication Publié, 1966
Article révisé par les pairs
| Résumé : | A local thermodynamical investigation of the real dissociation constant K in the diffuse layer shows that it is theoretically possible to calculate the ratio Κ/Κ′, where Κ′ is the dissociation constant in the bulk phase. This ratio is a function of the field intensity. According to the values of the polarization terms and of the molar volumes of the components, the dissociation constant Κ in the double layer can be greater, equal or smaller than the one in the bulk. |
