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High resolution spectroscopy and preliminary global analysis of CH stretching vibrations of C2H4 in the 3000 and 6000 cm-1 regions

par Lorono Gonzales, M.-A.;Boudon, V.;Loete, M.;Rotger, M.;Bourgeois, M.-T.;Didriche, Keevin ;Herman, Michel ;Kapitanov, V.A.;Ponomarev, Yu N.;Solodov, A.A.;Solodoc, A.M.;Petrova, T
Référence Journal of quantitative spectroscopy & radiative transfer, 111, 15, page (2265-2278)
Publication Publié, 2010

Article révisé par les pairs

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Résumé :

Ethylene (ethene, H2C=CH2) is a naturally occurring compound in ambient air that affects atmospheric chemistry and global climate. The C2H4 spectrum is available in databases only for the 1000 and 3000cm-1 ranges. In this work, the ethylene absorption spectrum was measured in the 6030-6250cm-1 range with the use of a high resolution Bruker IFS 125HR Fourier-spectrometer and a two-channel opto-acoustic spectrometer with a diode laser. As a secondary standard of wavelengths, the methane absorption spectrum was used in both cases.A preliminary analysis was realized thanks to the tensorial formalism developed by the Dijon group that is implemented in the XTDS software package [39]. We considered the two combination bands ν5+ν9 and ν5+ν11 as an interacting dyad. Parameters for the ν9/ν11 dyad were fitted simultaneously from a re-analysis of previously recorded supersonic expansion jet FTIR data, while parameters for the v5=1 Raman level were taken from literature. More than 600 lines could be assigned in the 6030-6250cm-1 region (and also 682 in the 2950-3150cm-1 region) and effective Hamiltonian parameters were fitted, including Coriolis interaction parameters. The dyad features are globally quite well reproduced, even if there are still problems at high J values. © 2010 Elsevier Ltd.