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Exact solution of a deterministic model for isomerization kinetics

par Elskens, Yves ;Frisch, Harry L.;Nicolis, Grégoire
Référence Journal of Statistical Physics, 33, 2, page (317-339)
Publication Publié, 1983

Article révisé par les pairs

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Résumé :

Isomerization kinetics is studied on a one-dimensional ideal gas model with deterministic transitions. The concentrations of species are found to satisfy the phenomenological rate laws appropriate for diffusion-controlled kinetics, and the various correlations are determined. In the long-time regime, higher correlations present long tails reflecting a strongly non-Markovian evolution. © 1983 Plenum Publishing Corporation.