• Citer

The role of H-bonds in the solid state organization of [1]benzothieno[3,2-b] [1]benzothiophene (BTBT) structures: Bis(hydroxy-hexyl)-BTBT, as a functional derivative offering efficient air stable organic field effect transistors (OFETs)

par Roche, Gilles H;Tsai, Yu-Tang;Clevers, Simon ;Thuau, Damien;Castet, Frederic;Geerts, Yves ;Moreau, Joel J.E.;Wantz, Guillaume;Dautel, Olivier
Référence Journal of Materials Chemistry C, 4, 28, page (6742-6749)
Publication Publié, 2016

Article révisé par les pairs

• Accès en ligne
• Détails
• Contenu
• Statistiques

Résumé :

The study of a [1]benzothieno[3,2-b][1]benzothiophene (BTBT) derivative decorated with hexyl chains functionalized with hydroxyl end groups is reported. A rapid and inexpensive functionalization of the BTBT in positions 2 and 7 has been developed. This compound is able to self-organize into a lamellar structure through σ-π stacking and van der Waals interactions but also through hydrogen bonding interactions. The hydrogen-bonded network controls the interlamellar region in terms of organization and stability. The liquid-crystal phase and structural changes observed by DSC have been characterized using an original approach combining FTIR and powder XRD measurements as a function of temperature. Thermally evaporated diol based OFETs exhibited good mobilities of up to 0.17 cm2 V-1 s-1 measured under an inert atmosphere but also in ambient air. The diol derivative is considered to be a very promising platform for the design of new functionalized BTBT.