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Regio- and stereoselective tether-directed remote functionalization of C60 with derivatives of the Tröger base

par Sergueev, Serguei ;Diederich, François
Référence Angewandte Chemie, 43, 13, page (1738-1740)
Publication Publié, 2004-03

Article révisé par les pairs

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Résumé :

Bringing two fascinating molecules together: Bismalonate derivatives of the Tröger base were used in the high-yielding regio- and diastereoselective preparation of bisadducts of C60 with trans-1, trans-2, and trans-4 addition patterns (e.g. see structure). Moreover, both enantiomers of the inherently chiral trans-2 adduct were prepared from enantiomerically pure tethers.