Experimental characterization and mondeling of hazards, BLEVE and BOILOVER

The objective of this thesis is to study the apparition criteria and the consequences of an accident involving a container of pressure liquefied gas (BLEVE phenomenon) or liquid fuels (Boilover phenomenon). After a bibliographic research on the two phenomena, an experimental study in laboratory scale is conducted and from the results, the phenomena and their hazards are modeled. Small scale experiments are performed in the BABELs facility (Bleve And Boilover ExperimentaL setup) that consists of a cylindrical chamber of 2m diameter and 3m high, with round shape flanges, made out of steel with a rated pressure of 0.5 MPa. It has 3 series of 7 optical accesses, an entrance door, and an optional air venting system.

A Boilover is a violent ejection of fuel due to the vaporization of a water sublayer, resulting in an enormous fire enlargement and formation of fireball and ground fire. Small scale experiments with cylindrical reservoirs of 0.08 to 0.3m diameter in glass or metal, filled with a mixture of diesel and oil have been performed. Instrumentation of the measurements consists of thermocouples rake, Medtherm radiometers, load cell and CCD or high-speed camera with a fisheye. During the quasi-steady combustion prior the Boilover, the typical variables describing a pool fire like burning rate, flame size, puffing frequency and radiation can be predicted with semi-empirical correlations available in the literature. At Boilover onset, high speed visualizations in glass reservoir show that the growth of one big bubble leads to a boiling front that propagates radially all along the fuel-water interface, ejecting the upper fuel layer and leading to the increase of flame size. LS-PIV technique applied to high-speed camera images shows that the flame enlargement is directly linked to the velocity of the flame.

A BLEVE (or Boiling Liquid Expanding Vapour Explosion) is an explosion resulting from the catastrophic failure of a vessel containing a liquid at a temperature significantly above its boiling point at normal atmospheric pressure. Small scale experiments are performed with cylinders of 42g of propane, laid horizontally and heated from below by an electrical resistor. A groove of the reservoirs on the upper part allows better reproducibility of the rupture. High speed visualization and shadowgraphy are helping in visualizing the rupture and the content release. Thermocouples and PCB are also used to measure respectively the temperature and the blast wave overpressure. These experiments show that the fluid behavior during rupture differs with the size of the weakened part and therefore with the rupture pressure. The internal pressure measurement showed that the rupture pressure and temperature are supercritical, leading to the definition of a new type of BLEVE since there is no distinction between liquid and vapor phases prior rupture.