Résumé : Measurements of the neutron removal and cluster breakup cross sections for the neutron-rich nuclei 14Be and 14B have been performed at 34.4 and 40.8 MeV/nucleon, respectively. Enhancement of the first chance cluster breakup cross section for 14Be compared to that of 14B provides evidence for a well-developed He cluster structure of the ground state of 14Be. Measurements of both the cross sections and decay-particle velocities suggest that multistep processes play an important role in the excitation and decay of both 14B and 14Be.