Résumé : The rare radiative decay ω→ π0π0γ has been detected with the GAMS-2000 multiphoton spectrometer at the IHEP 70 GeV accelerator. The ω → π0γ decay events have been used for normalization. The measured branching ratio is BR(ω → π0π0γ) = (7.2 ± 2.6) × 10-5.