par Frankin, J.A.;Huybrechts, Guy
Référence International journal of chemical kinetics, 1, 1, page (3-9)
Publication Publié, 1969
Article révisé par les pairs
Résumé : CCl and CC bond energies in the chloroethanes and CH, CCl, and CC bond energies in the chloroethyl radicals are calculated from known heats of formation of chloroethanes and chloroethylenes and known CH bond energies in chloroethanes. The results obtained show a dependence of bond energy on the isomeric structure of the molecules and radicals and on the type of bond broken (primary, secondary, or tertiary). Heats of formation and bond energies estimated from group property additivity rules are in close agreement with experimental values. Copyright © 1969 John Wiley & Sons, Inc.