par Frankin, J.A.;Huybrechts, Guy
Référence International journal of chemical kinetics, 1, 1, page (3-9)
Publication Publié, 1969
Référence International journal of chemical kinetics, 1, 1, page (3-9)
Publication Publié, 1969
Article révisé par les pairs
Résumé : | CCl and CC bond energies in the chloroethanes and CH, CCl, and CC bond energies in the chloroethyl radicals are calculated from known heats of formation of chloroethanes and chloroethylenes and known CH bond energies in chloroethanes. The results obtained show a dependence of bond energy on the isomeric structure of the molecules and radicals and on the type of bond broken (primary, secondary, or tertiary). Heats of formation and bond energies estimated from group property additivity rules are in close agreement with experimental values. Copyright © 1969 John Wiley & Sons, Inc. |